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          歐盟委員會發布CLP附件VI修訂草案,54個物質統一分類受影響

          來源 瑞旭集團 作者

          ECHA風險評估委員會就引入或更新某些物質的統一分類和標簽發布意見,并在發布修訂以前,向成員國和利益相關者征集意見。本次擬采納意見的物質有54個,清單見附表。

          歐盟委員會曾收到利益相關方對1,4-苯二胺、N,N'-混合Ph、甲苯基衍生物、二丁基氧化錫的科學評估提出的質疑。經評估,額外的信息不足以質疑其科學評估。因此,引入有關物質的統一分類和標簽是適當的。

          另外,數據表明鉛塊在水中的溶解度低于鉛粉,根據法規(EC)1272/2008附件I第4部分的計算得出的鉛塊分類不夠嚴格。因此,就M因子而言,修改鉛粉已有的水生毒性分類是合適的,并對鉛塊引入不同的水生毒性分類。

          關于甲基丙烯酸甲酯的呼吸道致敏物分類,碳酸鋰、氯化鋰和氫氧化鋰作為生殖毒性物質的分類,委員會也收到了利益相關方的補充信息。由于新信息還需進一步評估,上述4種物質在現階段不應進行統一的分類和標簽。

          此次分類修訂,歐盟也給予了供應商一段過渡期,用來調整產品的標簽和包裝,并根據現有的監管要求銷售現有庫存。供應商也可以在本條例適用日期前自愿應用新的分類。本法規將會在《歐盟官方公報》上公布后第20天生效,并將在生效后的18個月后開始適用。

          附表:

          序號

          物質名稱

          1. 

          benzyl(diethylamino)diphenylphosphonium 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxyphenyl)propan-2-yl]phenolate

          2. 

          benzyltriphenylphosphonium, salt with 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[phenol] (1:1)

          3. 

          reaction mass of 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphenol and benzyl(diethylamino)diphenylphosphonium 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxyphenyl)propan-2-yl]phenolate (1:1)

          4. 

          reaction mass of 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphenol and benzyltriphenylphosphonium, salt with 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[phenol] (1:1)

          5. 

          4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphenol; bisphenol AF

          6. 

          cinnamaldehyde; 3-phenylprop-2-enal; cinnamic aldehyde; cinnamal [1], (2E)-3-phenylprop-2-enal [2]

          7. 

          benfluralin (ISO); N-butyl-N-ethyl-α,α,α-trifluoro-2,6-dinitro-p-toluidine

          8. 

          3,3'-dimethylbiphenyl-4,4'-diyl diisocyanate

          9. 

          foramsulfuron (ISO); 2-{[(4,6-dimethoxypyrimidin-2-yl)carbamoyl]sulfamoyl}-4-formamido-N,N-dimethylbenzamide; 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-dimethylcarbamoyl-5-formamidophenylsulfonyl)urea

          10. 

          ethyl acrylate

          11. 

          methyl acrylate; methyl propenoate  

          12. 

          methyl methacrylate; methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate

          13. 

          transfluthrin (ISO); 2,3,5,6-tetrafluorobenzyl (1R,3S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

          14. 

          allyl methacrylate; 2-methyl-2-propenoic acid 2-propenyl ester

          15. 

          mepiquat chloride (ISO); 1,1-dimethylpiperidinium chloride

          16. 

          triethylamine

          17. 

          di-n-butylamine

          18. 

          4-nitrosomorpholin

          19. 

          difenoconazole (ISO); 1-({2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazole; 3-chloro-4-[(2RS,4RS;2RS,4SR)-4-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)-1,3-dioxolan-2-yl]phenyl 4-chlorophenyl ether

          20. 

          N,N-dimethyl-p-toluidine

          21. 

          potassium chlorate

          22. 

          sodium chlorate

          23. 

          reaction mass of 1-(2,3-epoxypropoxy)-2,2-bis ((2,3-epoxypropoxy)methyl) butane and 1-(2,3-epoxypropoxy)-2-((2,3-epoxypropoxy)methyl)-2-hydroxymethyl butane

          24. 

          metribuzin (ISO); 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one; 4-amino-4,5-dihydro-6-(1,1-dimethylethyl)-3-methylthio-1,2,4-triazin-5-one

          25. 

          lithium carbonate [1] lithium chloride [2] lithium hydroxide [3]

          26. 

          dimethyl propylphosphonate

          27. 

          dibutyltin maleate

          28. 

          dibutyltin oxide

          29. 

          clothianidin (ISO); (E)-1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine

          30. 

          cymoxanil (ISO); 2-cyano-N-[(ethylamino)carbonyl]-2-(methoxyimino)acetamide

          31. 

          nonylphenol, branched and linear, ethoxylated (with average molecular weight < 352 g/mol) [includes ortho-, meta-, para- isomers or any combination thereof]

          32. 

          nonylphenol, branched and linear, ethoxylated (with 352 g/mol ≤ average molecular weight < 704 g/mol) [includes ortho-, meta-, para- isomers or any combination thereof]

          33. 

          nonylphenol, branched and linear, ethoxylated (with 704 g/mol ≤ average molecular weight ≤ 1540 g/mol) [includes ortho-, meta-, para- isomers or any combination thereof]

          34. 

          1-phenylethan-1-one (1-phenylethylidene)hydrazone

          35. 

          9-[2-(ethoxycarbonyl)phenyl]-3,6-bis(ethylamino)-2,7-dimethylxanthylium chloride; Basic Red 1

          36. 

          picolinafen (ISO); N-(4-fluorophenyl)-6-[3-(trifluoromethyl)phenoxy]pyridine-2-carboxamide; 4′-fluoro-6-[(α,α,α-trifluoro-m-tolyl)oxy]picolinanilide

          37. 

          diuron (ISO); 3-(3,4-dichlorophenyl)-1,1-dimethylurea

          38. 

          diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide

          39. 

          hydrogen sulphide, hydrogen sulfide

          40. 

          benzyl alcohol

          41. 

          resorcinol; 1,3-benzenediol

          42. 

          2,2',6,6'-tetrabromo-4,4'-isopropylidenediphenol; tetrabromobisphenol-A

          43. 

          a reassessment at the request of the Commission to review the harmonised classification of lead (environment) -

          44. 

          2,2'-[[3-methyl-4-[(4-nitrophenyl)azo]phenyl]imino]bisethanol

          45. 

          3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctan-1-ol

          46. 

          1,4-Benzenediamine, N,N'-mixed Ph and tolyl derivs.; Reaction mass of N-phenyl,N’-o-tolyl-phenylene diamine, N,N’-diphenyl-p-phenylene diamine and N,N’-di-o-tolyl-phenylene diamine

          47. 

          tetramethylene dimethacrylate

          48. 

          7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl bismethacrylate

          49. 

          2,2'-ethylenedioxydiethyl dimethacrylate

          50. 

          bifenox (ISO); methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate

          51. 

          4-methylimidazole

          52. 

          sulfur dioxide

          53. 

          1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one

          54. 

          benalaxyl (ISO); methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)-DL-alaninate

           

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